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How do Peeps react to different temperatures? Make your own Peep slime!

2/21/2019

Author: Maddie Van Beek

Peeps and Temperature
Last week was Valentine’s Day, so you may have some leftover candy to use up! One classic Valentine’s Day Candy you might have is marshmallow Peeps (you might see these more at Easter, but the heart ones have become popular!). How exactly are Peeps (or any marshmallows) made?

List the ingredients that you think might be in marshmallows.

The answer: Sugar, gelatin, water, and AIR. Marshmallows are mostly made of sugar that has been whipped to include lots of tiny air bubbles. Marshmallows start out as a liquid sugar mixture, and then gas is incorporated to form an airy foam. In the past, marshmallows used to contain the root of the marsh-mallow plant for medicinal reasons, but you won’t find any marsh-mallow root in most marshmallows you see today. Now, we mostly enjoy marshmallows as a fun, sweet treat.

Heat a Peep!
What happens when you heat something? Molecules begin to move faster as they are heated, which causes them to expand. When something is cooled, the molecules begin to slow down and become more uniform.

When you heat a marshmallow, those air pockets that are already part of the foam expand, which causes your marshmallow to expand! As it cools back down, the marshmallow shrinks in size. If the marshmallow expands too much those air pockets burst, and the marshmallow cannot re-expand.

Here is some more information about what happens when you heat a marshmallow:
https://www.exploratorium.edu/cooking/candy/activity-mallows.html

Let’s test this out!

1. Tear apart a row of Peeps (you’ll need 3 Peeps).

2. Measure each Peep and make sure they are the same size. (We found that each heart-shaped Peep was 4.25 cm across at the widest point.)

3. Place one Peep in the freezer. Wait for 10 minutes.

4. Leave one Peep on a plate at room temperature. This is your control Peep. You will compare your results from the freezer Peep and microwaved Peep to see how size has changed.

5. Make your predictions! Will the freezer Peep change in size? Why? Will a heated Peep change in size? Why? Think about what you read.

6. After your 10 minutes is up, remove the freezer Peep. Below, the one on the left is the freezer Peep. The one on the right is the control Peep. The freezer Peep did not shrink noticeably.

7. Heat the remaining Peep in the microwave for 1 minute. Watch what happens!

8. Record your results.

Findings: We found that the freezer Peep stayed about the same size, but felt much firmer; the air molecules probably condensed and the cold made the sugar molecules lose their elasticity, making the marshmallow denser. The heated Peep grew immensely in size! The measurement across was over 7 cm, but it also expanded in height and length. It grew to its largest size after about 40 seconds. Once the Peep cooled, it was small, dry and crunchy. If you break it open, you might even see that it's a little burnt inside.

Next, you’re going to heat the remainder of your Peeps to make some Peep slime!

Notice that Peeps are made of sugar, corn syrup, and gelatin. All ingredients that we’ve used to make slime in the past!

YOU WILL NEED:
* Peeps (at least 5)
* Corn starch
* Powdered sugar
* Microwave safe bowl

Here’s what to do!

1. Tear apart at least five Peeps and put them in a microwave safe bowl.

2. Add 1 tablespoon of vegetable oil.
3. Heat your Peeps for 30 seconds. Watch what happens as they heat up!

4. Remove your Peeps from the microwave and stir them lightly with a spoon.

5. Sprinkle 1 tablespoon of corn starch into your Peeps and continue stirring. Note any texture changes.

6. Sprinkle a second tablespoon of starch into the Peeps—at this point, you may need to start mixing with your hands. Fun!

7. What does your slime look like? Feel like?

8. Add a final tablespoon of starch and your slime should be ready to go!

9. Add sprinkles for more fun!

10. What do you think happens if you reheat your slime? Try it!

11. We noticed it got a lot more goopy and sticky. Why do you think this is? Remember, your marshmallows started out with a lot of air bubbles… what do you think is happening as you continue to heat and play with the marshmallow slime? Add cornstarch again to get more of a dough-like feel.

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Exploring the Mpemba Effect

2/6/2019

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Author: Maddie Van Beek

Fargo has been FROZEN the last few weeks! In the spirit of winter, we’re going to learn about a few frozen phenomena.

These are the questions we'll be exploring today!

What is a polar vortex?
What is wind chill, and how does it work?
What is the Mpemba effect?
What freezes faster, hot water or cold water? Why do you think that?

Make some predictions. Write down what you know about each question.

First of all, let's talk about the Polar Vortex.
Maybe you’ve never heard of a polar vortex before, but they exist at the poles all the time! A polar vortex is a large, low-pressure area of cold air located near the North and South Poles. In the winter, the Northern polar vortex sometimes weakens and expands. Below, the picture on the left shows a strong polar vortex that is well defined. On the right is an example of a weak polar vortex that has expanded.

This expansion causes especially cold temperatures, which is what we’ve been dealing with lately. So if you hear the term “polar vortex,” don’t worry! This is nothing new! We just have to dress extra warm and be careful when it’s this cold outside.
Check out Scijinks (https://scijinks.gov/polar-vortex/) for a great explanation of how a Polar Vortex works!

Windchill
Because of this polar vortex, you might have heard people talking about the intense wind chill that we've been having. A -10 degree (Fahrenheit) day with a little extra wind suddenly feels much colder! So, does windchill affect everything? Will objects freeze faster because of higher windchill? This is a tricky question. Only living things are affected by windchill. That's why you see the term "real feel" when there is a significant windchill. The air stays the same temperature, but living things feel colder because of the wind.

Check out the windchill chart below. What do you notice? When the air is warmer, high wind speed doesn’t make as much of a difference in wind chill. When it’s cold, however, a little wind goes a long way!

When you go outside, the windchill can be dangerous because you FEEL as though the air temperature is much colder. Inanimate objects, however, only cool down to the air temperature. For example, if you leave a glass of water outside when it is 34 degrees, but it "feels like" 20 due to the wind chill, the water will not freeze. The wind DOES cool inanimate objects down more quickly than if the air was still, but it will only ever cool to the air temperature.

Mpemba Effect
Now, let’s go back to one of our first questions: which freezes first, hot water or cold water? You might have predicted that cold water would freeze before hot water, because that seems like the most logical answer! The hot water should take longer to cool off and get to freezing temperature than cold water, right? Well, sometimes that's not the case. In certain circumstances, hot water can freeze more quickly than cold water. This is called the Mpemba Effect.

The history behind the Mpemba Effect started with ice cream. Erasto Batholomeo Mpemba noticed in 1963 that when he put hot ice cream mixture and cold ice cream mixture in the freezer, the hot mixture sometimes froze more quickly. This sparked more interest in studying which water temperatures freeze faster.

There are many explanations suggested for the Mpemba effect. One is that some of the heated water evaporates, so less liquid ends up needing to be frozen than the same amount of cold water. Another is that cold water tends to freeze from the top down, while warm water freezes from the bottom up. In the first case, the top layer of ice insulates the rest of the water, and thus the water takes longer to freeze. Density is another factor that has been suggested; hot water is less dense which could allow for quicker cooling.

Unfortunately, the Mpemba Effect is yet to be fully explained! Results are often inconsistent, making it hard to understand exactly why hot liquid sometimes freezes faster. Can you explain the Mpemba Effect? Test it out for yourself!

YOU WILL NEED:
* 4 identical containers with caps
* Tape and writing utensil
* Paper to write down your observations
* Water
* Freezer or temperatures colder than 32 degrees Fahrenheit.

Here's what to do!
1. Gather your four identical containers. Label two of them "hot" and two of them "cold."

2. Turn your water on, and let it get as cold as possible.
3. Measure 1/2 cup of water and pour it carefully into your first container labeled “cold”. Seal with the lid. (If you don't have lids for your containers, use plastic wrap).
4. Measure 1/2 cup of cold water and pour into your second “cold” container. Leave this container open.
5. Turn your faucet to the hot setting, and measure 1/2 cup of hot water into the container labeled “hot”. Seal with the lid.
6. Repeat with the second “hot” container, but leave the lid off.

7. Place all four containers outside on an even surface (or in the freezer if you live somewhere warm).
8. Write down your prediction. In which order will the containers freeze? Why?
9. Set your timer and check on your containers every 15 minutes. Write down your observations.
10. After 90 minutes (when you can see significant freezing taking place) bring your containers inside. Which container contains the most ice? The least ice? Which one started to freeze first? Last? Do your results match your prediction?

Observations for round 1:
After 15 minutes, the hot containers had melted into the snow, but no freezing had taken place. Notice the condensation in the containers, especially in the ones with hot water.

After 30 minutes, the Cold/Open container formed a thin layer of ice at the surface.

The hot/open container had a nice layer of frost where the water evaporated, but the surface was not frozen.

After 45 minutes, the cold/open and the cold/closed containers clearly had a layer of ice at the surface. The hot/open and hot/closed still did not.

After an hour, the hot/open and hot/closed containers finally had thin layers of ice.

Results after 90 minutes (in order of most frozen to least)
We broke up the ice in order to tell which had frozen the most.

We repeated the tests four times, and the results of tests 2, 3, and 4 were the same.

If you’re having trouble being able to see which is more frozen, hold the containers up to the light (you can see the water moving) or look at the bottom of the containers.

Findings:
In our testing, we never observed the Mpemba effect. We repeated the test four times under the conditions below.
1. 1 cup of water/container outside in -20 degrees F, 3 mph wind, on snow.
2. 1/4 cup of water/container in -20 degrees F, 7 mph wind, on baking sheet.
3. 1/2 cup of water/container in -20 degrees F, 10 mph wind, on baking sheet.
4. 1/2 cup of water/container in a normal freezer (no wind).
However, we DID determine that the open containers froze faster than their sealed counterparts. Each time the order of freezing was cold/open, cold/closed, hot/open, hot/closed. Why do you think that might be?

Another note: The cold containers froze from the surface first, while the Hot containers seemed to freeze more uniformly from the sides of the bottles.

Did you observe the Mpemba effect? If not, what factors might be worth testing? You could try the same experiment with different containers (example: glass instead of plastic or wide mouth instead of narrow).

Images:
Polar Vortex and Windchill Chart are Public Domain images found in Wikimedia Commons.
Photographs of experiment taken by Maddie Van Beek.

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How do Peeps react to different temperatures? Make your own Peep slime!

Exploring the Mpemba Effect

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